It's even stranger that I'm on the mailing list..... which model NAS?
As per usual, I've only got the linux/open source viewpoint, but that UPS seems widely supported and the configurata will be much the same....ie; configure your UPS monitoring software on the PC to generate an SNMP message to send to the NAS telling it mains power is OFF and UPS is active, and NAS should shutdown....(and there may also be a SNMP message the NAS can respond to when mains power comes good).
HTH
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